Structure and nitrite reduction reactivity study of bio-inspired copper(i)–nitro complexes in steric and electronic considerations of tridentate nitrogen ligands

Author:

Chang Yu-Lun12345,Lin Ya-Fan12346,Chuang Wan-Jung1234,Kao Chai-Lin12345ORCID,Narwane Manmath1234,Chen Hsing-Yin1234ORCID,Chiang Michael Y.12345,Hsu Sodio C. N.12347ORCID

Affiliation:

1. Department of Medicinal and Applied Chemistry

2. Kaohsiung Medical University

3. Kaohsiung 807

4. Taiwan

5. Department of Chemistry

6. Department of Fragrance and Cosmetic Science

7. Department of Medical Research

Abstract

Two bio-inspired copper(i)–nitro complexes bearing steric bulky neutral Tpm3-tBu and anionic Tp3-tBu were synthesized to release NO gas under acidic conditions.

Funder

Ministry of Science and Technology, Taiwan

National Sun Yat-sen University

Kaohsiung Medical University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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