Biomimetic catalysis of nitrite reductase enzyme using copper complexes in chemical and electrochemical reduction of nitrite

Author:

Ferreira Millena P.1,Castro Caio B.1,Honorato João23,He Sheng4,Gonçalves Guimarães Júnior Walber1ORCID,Esmieu Charlene5,Castellano Eduardo E.3,de Moura André F.1,Truzzi Daniela R.2ORCID,Nascimento Otaciro R.3,Simonneau Antoine5ORCID,Marques Netto Caterina G. C.14ORCID

Affiliation:

1. Department of Chemistry, Universidade Federal de São Carlos (UFSCar), Rod. Washington Luiz, km 235 s/n, CEP 13565905 São Carlos, SP, Brazil

2. Insitututo de Química, Departamento de Bioquímica, Universidade de São Paulo (USP), Av. Prof. Dr. Lineu Prestes, 748, CEP 05513-970 São Paulo, SP, Brazil

3. Instituto de Física, Universidade de São Paulo (USP), Av.João Dagnone, 1100, CEP 13563-120, São Carlos, SP, Brazil

4. Department of Chemistry, Emory University, 1515 Dickey Drive, 30322 Atlanta, GA, USA

5. LCC-CNRS, Universite de Toulouse, CNRS, UPS, 205 route de Narbonne, F31077 Toulouse cedex 4, France

Abstract

Copper nitrite reductase mimetics were shown to have their catalysis influenced by the secondary coordination sphere and hydrogen bonding.

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Fundação de Amparo à Pesquisa do Estado de São Paulo

Conselho Nacional de Desenvolvimento Científico e Tecnológico

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference55 articles.

1. M.Kern and J.Simon , in Methods in Enzymology , Elsevier , 2011 , vol. 486 , pp. 429–446

2. E. v.Faassen , A. F.Vanin and A.Slama-Schwok , Nitrite as Endothelial NO Donor under Anoxia , Elsevier B.V , 2007

3. Nitric Oxide in Health and Disease of the Nervous System

4. Emerging artificial nitrogen cycle processes through novel electrochemical and photochemical synthesis

5. Β-Cyclodextrin-graft-poly(amidoamine) dendrons as the nitric oxide deliver system for the chronic rhinosinusitis therapy

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