Influence of spin state and electron configuration on the active site and mechanism for catalytic hydrogenation on metal cation catalysts supported on NU-1000: insights from experiments and microkinetic modeling

Author:

Shabbir Hafeera1234ORCID,Pellizzeri Steven5674,Ferrandon Magali89104,Kim In Soo119124,Vermeulen Nicolaas A.1314154,Farha Omar K.1314154ORCID,Delferro Massimiliano89104ORCID,Martinson Alex B. F.119124ORCID,Getman Rachel B.1234ORCID

Affiliation:

1. Chemical and Biomolecular Engineering

2. Clemson University

3. Clemson

4. USA

5. Department of Chemistry and Biochemistry

6. Eastern Illinois University

7. Charleston

8. Chemical Sciences and Engineering Division

9. Argonne National Laboratory

10. Argonne

11. Materials Science Division

12. Lemont

13. Department of Chemistry and International Institute for Nanotechnology

14. Northwestern University

15. Evanston

Abstract

Spin state is found to determine the mechanism and active site of catalytic hydrogenation on metal cation catalysts.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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