A diamagnetic iron complex and its twisted sister – structural evidence on partial spin state change in a crystalline iron complex

Author:

Salojärvi Esko1,Peuronen Anssi1ORCID,Moilanen Jani2ORCID,Huhtinen Hannu3,Lindén Johan4ORCID,Mansikkamäki Akseli5ORCID,Lastusaari Mika1ORCID,Lehtonen Ari1ORCID

Affiliation:

1. Inorganic Materials Chemistry research group, Department of Chemistry, University of Turku, FI-20014 Turku, Finland

2. Department of Chemistry, University of Jyväskylä, P.O. Box 35, FI-40014 Jyväskylä, Finland

3. Wihuri Physical Laboratory, Department of Physics and Astronomy, University of Turku, FI-20014 Turku, Finland

4. Faculty of Science and Engineering/Physics, Åbo Akademi University FI-20500, Turku/Åbo, Finland

5. NMR Research Unit, University of Oulu, P. O. Box 3000, 90014 Oulu, Finland

Abstract

Diamagnetic Fe complex was made of a redox non-innocent ligand precursor N,N′-bis(3,5-di-tert-butyl-2-hydroxy-phenyl)-1,2-phenylene-diamine and FeCl3. Its phenoxazine derivative was obtained via intra-ligand cyclisation of the parent complex.

Funder

Magnus Ehrnroothin Säätiö

Walter Ahlströmin Säätiö

Academy of Finland

Oulun Yliopisto

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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