Ni(<scp>ii</scp>) complexes of a new tetradentate NN′N′′O picolinoyl-1,2-phenylenediamide-phenolate redox-active ligand at different redox levels-Reference-Cited by-同舟云学术

Ni(ii) complexes of a new tetradentate NN′N′′O picolinoyl-1,2-phenylenediamide-phenolate redox-active ligand at different redox levels

Published:2022 Issue:23 Volume:51 Page:9017-9029
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mukhopadhyay Narottam¹^ORCID,Sengupta Arunava²,Vijay Aswin Kottapurath¹,Lloret Francesc³,Mukherjee Rabindranath⁴^ORCID

Affiliation:

1. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, West Bengal 741 246, India

2. Department of Chemistry, Techno India University, West Bengal, Kolkata 700091, India

3. Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMOL), Universitat de València, Polígono de la Coma, s/n, 46980 Paterna, València, Spain

4. Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh 208016, India

Abstract

Using an asymmetric ligand [Ni(L2)]z (z = 0, 1+ and 1−) complexes have been synthesized and their molecular, electronic structures elucidated, supported by DFT calculations: [NiII{(L2)˙2−}], [NiII{(L2)−}]+ and [NiII{(L2)3−}]−.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Council of Scientific and Industrial Research, India

University Grants Commission

Indian Academy of Sciences

Indian National Science Academy

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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