Long-lived excited states of platinum(ii)-porphyrins for highly efficient photocatalytic hydrogen evolution

Author:

Bodedla Govardhana Babu123ORCID,Dong Yu4ORCID,Tang Geliang4ORCID,Zhao Jianzhang4ORCID,Zhang Fuxiang5ORCID,Zhu Xunjin3ORCID,Wong Wai-Yeung12ORCID

Affiliation:

1. Department of Applied Biology & Chemical Technology and Research Institute for Smart Energy, The, Hong Kong Polytechnic University, Hong Kong, P. R. China

2. The Hong Kong Polytechnic University Shenzhen Research Institute, Shenzhen 518057, P. R. China

3. Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University, Waterloo Road, Kowloon Tong, Hong Kong, P. R. China

4. School of Chemical Engineering and State Key Laboratory of Fine Chemicals Dalian University of Technology, Dalian 116024, P. R. China

5. State Key Laboratory of Catalysis, iChEM, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian 116023, P. R. China

Abstract

Naphthalimide (NI) conjugated Pt(ii)-porphyrins show high performances in cocatalyst-free photocatalytic hydrogen evolution (PHE) because of their long-lived excited states and strong light-harvesting capability.

Funder

Hong Kong Baptist University

National Natural Science Foundation of China

Hong Kong Polytechnic University

Research Grants Council, University Grants Committee

Science, Technology and Innovation Commission of Shenzhen Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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