Novel ruthenium complexes bearing bipyridine-based and N-heterocyclic carbene-supported pyridine (NCN) ligands: the influence of ligands on catalytic transfer hydrogenation of ketones-Reference-Cited by-同舟云学术

Novel ruthenium complexes bearing bipyridine-based and N-heterocyclic carbene-supported pyridine (NCN) ligands: the influence of ligands on catalytic transfer hydrogenation of ketones

Published:2022 Issue:1 Volume:51 Page:340-351
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Piyasaengthong Akkharadet¹²^ORCID,Williams Luke J.¹,Yufit Dmitry S.¹,Walton James W.¹^ORCID

Affiliation:

1. Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, UK

2. Bioscience program, Faculty of Science, Kasetsart University, Chatuchak, Bangkok 10900, Thailand

Abstract

A series of ruthenium complexes is presented. The complexes are designed as catalysts for transfer hydrogenation of ketones. The most active complexes show improvements upon commercially available catalysts. A mechanistic study is included.

Funder

Royal Society of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03240B

Reference45 articles.

1. The Golden Age of Transfer Hydrogenation

2. Effect of the Structure of the Diamine Backbone of P−N−N−P ligands in Iron(II) Complexes on Catalytic Activity in the Transfer Hydrogenation of Acetophenone

3. Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

4. Bis-N-heterocyclic carbene ruthenium(II) carbonyl complexes: Synthesis, structural characterization and catalytic activities in transfer hydrogenation of ketones

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