Role of Fe decoration on the oxygen evolving state of Co3O4 nanocatalysts

Author:

Haase Felix T.1,Ortega Eduardo1ORCID,Saddeler Sascha2,Schmidt Franz-Philipp3,Cruz Daniel3,Scholten Fabian1,Rüscher Martina1,Martini Andrea1,Jeon Hyo Sang1,Herzog Antonia1,Hejral Uta1ORCID,Davis Earl M.1ORCID,Timoshenko Janis1,Knop-Gericke Axel34,Lunkenbein Thomas3ORCID,Schulz Stephan2ORCID,Bergmann Arno1ORCID,Roldan Cuenya Beatriz1ORCID

Affiliation:

1. Department of Interface Science, Fritz Haber Institute of the Max Planck Society, Berlin, Germany

2. Institute for Inorganic Chemistry and Center for Nanointegration Duisburg-Essen [CENIDE], University of Duisburg-Essen, Essen, Germany

3. Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society, Berlin, Germany

4. Max-Planck-Institut für Chemische Energiekonversion, Stiftstrasse 34-36, 45470 Mülheim, Germany

Abstract

Electrocatalytic OER activity of Co3O4 is enhanced by Fe near-surface decoration with a more pronounced formation of Co–FeOx(OH)y reaction zones comprising distinct redox-active Fe3+ and Co2+ sites as shown by comprehensive operando studies.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

European Research Council

Publisher

Royal Society of Chemistry (RSC)

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