Dodecanuclear 3d/4f-metal clusters with a ‘Star of David’ topology: single-molecule magnetism and magnetocaloric properties

Author:

Alexandropoulos Dimitris I.1234,Cunha-Silva Luís56789,Lorusso Giulia10111213,Evangelisti Marco10111213,Tang Jinkui1415161718,Stamatatos Theocharis C.1234

Affiliation:

1. Department of Chemistry

2. Brock University

3. Ontario

4. Canada

5. REQUIMTE-LAQV & Department of Chemistry and Biochemistry

6. Faculty of Sciences

7. University of Porto

8. 4169-007 Porto

9. Portugal

10. Instituto de Ciencia de Materiales de Aragón (ICMA) and Departamento de Física de la Materia Condensada

11. CSIC-Universidad de Zaragoza

12. 50009 Zaragoza

13. Spain

14. State Key Laboratory of Rare Earth Resource Utilization

15. Changchun Institute of Applied Chemistry

16. Chinese Academy of Sciences

17. Changchun 130022

18. P. R. China

Abstract

The first dodecanuclear [MII6LnIII6] clusters with a ‘Star of David’ metal topology have been synthesized with a variety of different divalent 3d-metal ions and lanthanides, and exhibited single-molecule magnetism and magnetic refrigeration.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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