Formation of the spirocyclic, Si-centered cage cations [ClP(NSiMe3)2Si(NSiMe3)2P5]+ and [P5(NSiMe3)2Si(NSiMe3)2P5]2+-Reference-Cited by-同舟云学术

Formation of the spirocyclic, Si-centered cage cations [ClP(NSiMe3)2Si(NSiMe3)2P5]+ and [P5(NSiMe3)2Si(NSiMe3)2P5]2+

Published:2016 Issue:5 Volume:45 Page:1953-1961
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Holthausen M. H.¹²³⁴⁵,Weigand J. J.¹²³⁴⁵

Affiliation:

1. TU Dresden

2. Fachrichtung Chemie und Lebensmittelchemie

3. Professur für Anorganische Molekülchemie

4. 01062 Dresden

5. Germany

Abstract

A GaCl₃-mediated rearrangement of a bicyclic phosphorus–nitrogen–silicon heterocycle gives phosphenium ion intermediates which are suitable for the activation of P₄.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT01512J

Reference51 articles.

1. The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity

2. catena-Phosphorus Cations

3. Ligand-Stabilized [P4]2+Cations

4. One-Pot Syntheses of Cationic Polyphosphorus Frameworks with Two-, Three-, and Four-Coordinate Phosphorus Atoms by One-Pot Multiple PP Bond Formations from a P1 Source

5. Versatile Reagent Ph3As(OTf)2: One-Pot Synthesis of [P7(AsPh3)3][OTf]3from PCl3

Cited by 10 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Kinetically Stabilized Diarylpnictogenium Ions;ChemPlusChem;2023-01-20

2. Bicyclic and tricyclic phosphanes with p-block substituents;Reviews in Inorganic Chemistry;2021-04-27

3. Chain, ring, and cluster compounds of group 15 elements (P, As, Sb, Bi);Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2021

4. Synthesis and crystal structure of 1,3-di-tert-butyl-2-chloro-4,4-diphenyl-1,3,2λ3,4-diazaphosphasiletidine;Acta Crystallographica Section E Crystallographic Communications;2019-02-28

5. First experimental evidence for the elusive tetrahedral cations [EP3]+ (E = S, Se, Te) in the condensed phase;Chemical Science;2019