First experimental evidence for the elusive tetrahedral cations [EP3]+ (E = S, Se, Te) in the condensed phase
Author:
Affiliation:
1. Institut für Anorganische und Analytische Chemie
2. Freiburger Materialforschungszentrum (FMF)
3. Universität Freiburg
4. 79104 Freiburg
5. Germany
6. Institut für Physikalische Chemie
Abstract
Cationic tetrahedra: condensed phase access to the tetrahedral cations [EP3]+ (E = S, Se, Te) isoelectronic to P4 or AsP3 was found by the reactions of ECl3[WCA] with P4 ([WCA]− = [Al(ORF)4]− and [F(Al(ORF)3)2]−; –RF = –C(CF3)3).
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC03915E
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