Understanding titanium-catalysed radical–radical reactions: a DFT study unravels the complex kinetics of ketone–nitrile couplings
Author:
Affiliation:
1. Institut für Organische Chemie
2. Albert-Ludwigs-Universität Freiburg
3. 79104 Freiburg
4. Germany
5. Institut für Anorganische und Analytische Chemie
Abstract
A detailed DFT investigation gives fundamental insight into the mechanism of a low-valent titanium-catalysed radical–radical coupling.
Funder
Verband der Chemischen Industrie
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00643A
Reference106 articles.
1. Recent Advances in Radical C–H Activation/Radical Cross-Coupling
2. The Electron-Way: Metal-Catalyzed Reductive Umpolung Reactions of Saturated and α,β-Unsaturated Carbonyl Derivatives
3. Radicals and Transition-Metal Catalysis: An Alliance Par Excellence to Increase Reactivity and Selectivity in Organic Chemistry
4. Radicals in Organic Synthesis , ed. P. Renaud and M. P. Sibi , Wiley-VCH , Weinheim , 2001
5. Reagent-Controlled Transition-Metal-Catalyzed Radical Reactions
Cited by 18 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Selective Transformations Mediated by Group 4 Metal Cyclopentadienyl Complexes;Topics in Organometallic Chemistry;2024
2. Mechanistic Applications of Nonlinear Effects in First‐Row Transition‐Metal Catalytic Systems;Chinese Journal of Chemistry;2023-08-22
3. Reductive Umpolung and Defunctionalization Reactions through Higher-Order Titanium(III) Catalysis;Synlett;2022-12-23
4. A Catalytic Alkylation of Ketones via sp3 C–H Bond Activation;The Journal of Organic Chemistry;2022-06-01
5. Diastereoselective and enantioselective photoredox pinacol coupling promoted by titanium complexes with a red-absorbing organic dye;Chemical Science;2022
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3