Diastereoselective and enantioselective photoredox pinacol coupling promoted by titanium complexes with a red-absorbing organic dye

Author:

Calogero Francesco1,Magagnano Giandomenico1,Potenti Simone12ORCID,Pasca Francesco1,Fermi Andrea13ORCID,Gualandi Andrea13ORCID,Ceroni Paola13ORCID,Bergamini Giacomo1ORCID,Cozzi Pier Giorgio13ORCID

Affiliation:

1. Dipartimento di Chimica “Giacomo Ciamician”, Alma Mater Studiorum – Università di Bologna, Via Selmi 2, 40126 Bologna, Italy

2. Laboratorio SMART, Scuola Normale Superiore, Piazza dei Cavalieri 7, 56126, Pisa, Italy

3. Center for Chemical Catalysis – C3, Alma Mater Studiorum – Università di Bologna, Via Selmi 2, 40126 Bologna, Italy

Abstract

A metallaphotoredox, diastereoselective and enantioselective pinacol coupling reaction promoted by titanium complexes with the use of a red-absorbing organic dye was developed.

Funder

Chiesi Farmaceutici

Ministero dell’Istruzione, dell’Università e della Ricerca

University of Bologna

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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