Proton conductivity in mixed cation phosphate, KMg1−xH2x(PO3)·yH2O, with a layered structure at low-intermediate temperatures

Author:

Matsuda Yasuaki12345ORCID,Ueda Naoya12345,Funakoshi Kousei12345,Nakajima Jun12345,Mori Daisuke67895,Taminato Sou67895ORCID,Higashimoto Shinya12345

Affiliation:

1. Department of Applied Chemistry

2. Faculty of Engineering

3. Osaka Institute of Technology

4. Osaka

5. Japan

6. Department of Chemistry for Materials

7. Graduate School of Engineering

8. Mie University

9. Mie 514-8507

Abstract

Benitoite-type KMg1−xH2x(PO3)3·yH2O is a new proton conductor that exhibits high proton conductivity over 10−2 S cm−1 in the wide temperature range of 150–350 °C under a humidified atmosphere (pH2O = 3 kPa).

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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