Acid-promoted hydride transfer from an NADH analogue to a Cr(iii)–superoxo complex via a proton-coupled hydrogen atom transfer
Author:
Affiliation:
1. Department of Chemistry and Nano Science
2. Ewha Womans University
3. Seoul 03760
4. Korea
5. Faculty of Science and Engineering
6. Institute of Drug Discovery Technology
Abstract
Acid-promoted hydride transfer from an NADH analogue to a Cr(iii)–superoxo complex in the presence of acid proceeds via the full formation of the NADH analogue radical cation, followed by the decay of the radical, and accompanied then by the formation of NAD+.
Funder
National Research Foundation of Korea
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04004E
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