Rh nanoparticles from thiolate dimers: selective and reusable hydrogenation catalysts in ionic liquids-Reference-Cited by-同舟云学术

Rh nanoparticles from thiolate dimers: selective and reusable hydrogenation catalysts in ionic liquids

Published:2018 Issue:17 Volume:8 Page:4373-4382
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Serrano-Maldonado A.¹²³⁴⁵^ORCID,Rozenel S. S.¹²³⁴⁵,Jimenez-Santiago J. L.¹²³⁴⁵^ORCID,Guerrero-Ríos I.¹²³⁴⁵^ORCID,Martin E.¹²³⁴⁵

Affiliation:

1. Depto. de Química Inorgánica

2. Facultad de Química

3. Universidad Nacional Autónoma de México

4. 04510 CDMX

5. Mexico

Abstract

Thiolate-capped RhNPs in imidazolium-based ionic liquids were synthesized from [Rh(μ-SR)(COD)]₂ dimmers under H₂ pressure without external addition of ligand stabilizers, preserving thiolate integrity on the nanoparticle surface. This nanoparticulated systems showed a remarkable selectivity that led to their application in the one pot reductive N-alkylation to produce amines.

Funder

Dirección General de Asuntos del Personal Académico, Universidad Nacional Autónoma de México

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00227D

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