Design of novel chiral N,N,O-tridentate phenanthroline ligands and their application to enantioselective addition of organozinc reagents to aldehydes-Reference-Cited by-同舟云学术

Design of novel chiral N,N,O-tridentate phenanthroline ligands and their application to enantioselective addition of organozinc reagents to aldehydes

Published:2014 Issue:87 Volume:50 Page:13224-13227
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Naganawa Yuki¹²³⁴,Namba Tomoya¹²³⁴,Aoyama Tomotaka¹²³⁴,Shoji Kentaro¹²³⁴,Nishiyama Hisao¹²³⁴

Affiliation:

1. Department of Applied Chemistry

2. Graduate School of Engineering

3. Nagoya University

4. Chikusa, Japan

Abstract

The novel chiral N,N,O-tridentate ligands (BinThro) containing binaphthyl and phenanthroline units were developed. The enantioselective organozinc addition to aldehydes was performed in the presence of BinThro (S)-1 with up to 95% ee.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC05020G

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