Phen-2NO, a new C2-symmetric rigid-featured tetradentate ligand, and its application in the asymmetric alkylation reaction of indoles

Author:

Chen Zi-Yue1,Xu Ke-Lan1,Wang Xi-Rui1,Hu Pan1,Jiang Wei-Yan2,Dai Yi-Feng1ORCID,Peng Li-Jun1,Liu Xiong-Li1ORCID

Affiliation:

1. National & Local Joint Engineering Research Center for the Exploitation of Homology Resources of Southwest Medicine and Food, Guizhou University, Guiyang 550025, Guizhou, China

2. Guizhou Equipment Manufacturing Polytechnic, Guiyang 550025, Guizhou, China

Abstract

A new class of C2-symmetric rigid-featured chiral phen ligands that provide the N,N,O,O-tetradentate coordination of the phen moiety and two additional N,N-dioxides were rationally designed and developed.

Funder

Data Center of Management Science, National Natural Science Foundation of China - Peking University

Publisher

Royal Society of Chemistry (RSC)

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