Synthesis and characterization of non-bridging mono- and bis-σ-η1-alkynyl derivatives of the phosphido-bridged hexaplatinum core [Pt6(μ-PBut2)4(CO)4]2+-Reference-Cited by-同舟云学术

Synthesis and characterization of non-bridging mono- and bis-σ-η1-alkynyl derivatives of the phosphido-bridged hexaplatinum core [Pt6(μ-PBut2)4(CO)4]2+

Published:2016 Issue:16 Volume:45 Page:6878-6892
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bonuccelli Veronica¹²³⁴,Funaioli Tiziana¹²³⁴,Leoni Piero¹²³⁴,Marchetti Fabio¹²³⁴,Marchetti Lorella¹²³⁴,Pasquali Marco¹²³⁴

Affiliation:

1. Dipartimento di Chimica e Chimica Industriale

2. Università di Pisa

3. I-56124 Pisa

4. Italy

Abstract

Several mono- or bis-alkynyl derivatives of the [Pt₆(μ-PBu^t₂)₄(CO)₄]²⁺ core, pivotal intermediates in the synthesis of new cluster-containing oligomers, were prepared and fully characterized.

Funder

Fondazione Cassa di Risparmio di Pisa

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00410E

Reference110 articles.

1. Metal Alkynyl σ Complexes: Synthesis and Materials

2. An overview of the chemistry of homo and heteropolynuclear platinum complexes containing bridging acetylide (μ-C≡CR) ligands

3. Homoleptic transition metal acetylides