Spectroscopic observation of two-center three-electron bonded (hemi-bonded) structures of (H2S)n+ clusters in the gas phase
Author:
Affiliation:
1. Department of Chemistry
2. Graduate School of Science
3. Tohoku University
4. Sendai 980-8578
5. Japan
Abstract
The presence of a two-center three-electron (2c–3e) bonded (hemi-bonded) ion core in the (H2S)n+ cluster is revealed by infrared spectroscopy combined with ab initio calculations. The stability of the hemi-bonded ion core to solvation is also proved.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC05361K
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5. Structures and stabilities of singly charged three-electron hemibonded systems and their hydrogen-bonded isomers
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