An [FeIII30] molecular metal oxide

Author:

Dearle Alice E.1ORCID,Cutler Daniel J.1ORCID,Coletta Marco1ORCID,Lee Edward2,Dey Sourav3ORCID,Sanz Sergio1ORCID,Fraser Hector W. L.1ORCID,Nichol Gary S.1ORCID,Rajaraman Gopalan3ORCID,Schnack Jürgen4ORCID,Cronin Leroy2ORCID,Brechin Euan K.1ORCID

Affiliation:

1. EaStCHEM School of Chemistry, The University of Edinburgh, David Brewster Road, Edinburgh, EH9 3FJ, UK

2. WestCHEM School of Chemistry, The University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK

3. Department of Chemistry, Indian Institute of Technology Bombay, Mumbai, 400076, India

4. Fakultät für Physik, Universitat Bielefeld, Postfach 100131, D-33501 Bielefeld, Germany

Abstract

Dissolution of FeBr3 in a mixture of acetonitrile and 3,4-lutidine in the presence of an amine results in the formation of an [Fe30] molecular metal oxide containing alternating layers of tetrahedral and octahedral FeIII ions.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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