Balancing volumetric and gravimetric uptake in highly porous materials for clean energy-Reference-Cited by-同舟云学术

Balancing volumetric and gravimetric uptake in highly porous materials for clean energy

Published:2020-04-17 Issue:6488 Volume:368 Page:297-303
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Chen Zhijie¹^ORCID,Li Penghao¹^ORCID,Anderson Ryther²^ORCID,Wang Xingjie¹^ORCID,Zhang Xuan¹^ORCID,Robison Lee¹^ORCID,Redfern Louis R.¹^ORCID,Moribe Shinya¹³^ORCID,Islamoglu Timur¹^ORCID,Gómez-Gualdrón Diego A.²^ORCID,Yildirim Taner⁴,Stoddart J. Fraser¹⁵⁶^ORCID,Farha Omar K.¹⁷^ORCID

Affiliation:

1. Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.

2. Department of Chemical and Biological Engineering, Colorado School of Mines, Golden, CO 80401, USA.

3. Future Mobility Research Department, Toyota Research Institute of North America, Ann Arbor, Michigan 48105, USA.

4. NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA.

5. Institute for Molecular Design and Synthesis, Tianjin University, 92 Weijin Road, Tianjin 300072, China.

6. School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia.

7. Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.

Abstract

Delivering methane and hydrogen The pressure for onboard storage of methane and hydrogen on vehicles is usually limited to 100 bar for the use of lightweight containers, but the amount stored can be increased with the use of absorbent materials. Efficient storage and delivery require a balance of volumetric and gravimetric storage. Chen et al. designed a metal-organic framework with trialuminum nodes and a large hexadentate aromatic linker that optimizes both parameters. This material surpassed the U.S. Department of Energy targets for methane and had a deliverable capacity of 14% by weight for hydrogen. Science , this issue p. 297

Funder

Northwestern University

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference83 articles.

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