Total synthesis and complete configurational assignment of amphirionin-2-Reference-Cited by-同舟云学术

Total synthesis and complete configurational assignment of amphirionin-2

Published:2021 Issue:3 Volume:12 Page:872-879
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kato Shota¹²³⁴⁵,Mizukami Daichi¹²³⁴⁵,Sugai Tomoya¹²³⁴⁵,Tsuda Masashi⁶⁷⁸⁵,Fuwa Haruhiko¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry

2. Faculty of Science and Engineering

3. Chuo University

4. Tokyo 112-8551

5. Japan

6. Center for Advanced Marine Core Research and Department of Agriculture and Marine Science

7. Kochi University

8. Kochi 783-8502

Abstract

An extensive application of cobalt-catalyzed Mukaiyama-type cyclization of γ-hydroxy olefins and a late-stage Stille-type reaction enabled syntheses of four diastereomers of amphirionin-2 to establish its absolute configuration.

Funder

Japan Society for the Promotion of Science

Naito Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC06021F

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