A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation-Reference-Cited by-同舟云学术

A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation

Published:2021 Issue:14 Volume:13 Page:6902-6915
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Moraru Ionut-Tudor¹²³⁴⁵^ORCID,Martínez-Prieto Luis M.⁶⁷⁸⁹^ORCID,Coppel Yannick¹⁰¹¹¹²²¹³^ORCID,Chaudret Bruno¹²³⁴⁵^ORCID,Cusinato Lucy¹²³⁴⁵^ORCID,del Rosal Iker¹²³⁴⁵,Poteau Romuald¹²³⁴⁵^ORCID

Affiliation:

1. Université de Toulouse; INSA

2. UPS

3. CNRS; LPCNO (IRSAMC)

4. F-31077 Toulouse

5. France

6. Instituto de Tecnología Química (UPV-CSIC)

7. Universitat Politècnica de València

8. Valencia

9. Spain

10. CNRS

11. LCC (Laboratoire de Chimie de Coordination)

12. Université de Toulouse

13. INPT

Abstract

According to advanced ¹³C MAS NMR experiments and DFT investigations of multi-step pathways as well as DFT-based NMR assignment of experimental spectra, it is shown that carbide formation can occur on ruthenium NPs during CO bond cleavage.

Funder

European Social Fund

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NR/D0NR08735A

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