The hydrogen atom transfer reactivity of sulfinic acids-Reference-Cited by-同舟云学术

The hydrogen atom transfer reactivity of sulfinic acids

Published:2018 Issue:36 Volume:9 Page:7218-7229
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Griesser Markus¹²³⁴^ORCID,Chauvin Jean-Philippe R.¹²³⁴^ORCID,Pratt Derek A.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biomolecular Sciences

2. University of Ottawa

3. Ottawa

4. Canada K1N 6N5

Abstract

Sulfinic acids are characterized to be very good H-atom donors to each of alkyl and alkoxyl radicals. In order to participate in useful radical chain reactions, the sulfonyl radicals must undergo fast propagating reactions to avoid autoxidation, which is surprisingly rate-limited by the reaction of sulfonyl radicals with oxygen.

Funder

Canada Foundation for Innovation

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC02400F

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