A dinuclear Rh(−<scp>i</scp>)/Rh(<scp>i</scp>) complex bridged by biphilic phosphinine ligands-Reference-Cited by-同舟云学术

A dinuclear Rh(−i)/Rh(i) complex bridged by biphilic phosphinine ligands

Published:2023 Issue:32 Volume:14 Page:8524-8530
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Masada Koichiro¹^ORCID,Okabe Kiyosumi¹^ORCID,Kusumoto Shuhei¹^ORCID,Nozaki Kyoko¹^ORCID

Affiliation:

1. Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

A dinuclear Rh(−i)/Rh(i) complex bridged by tridentate phosphinine ligands was prepared by reduction of the corresponding Rh(i) complex. An unsymmetric bridging mode of the phosphinine differentiated the electronic environments of the Rh centres.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02292G

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