The case of a μ<sub>2</sub>-P aromatic phosphinine as a 4-electron donor forming σ- and π-three–center-two-electron bonds-Reference-Cited by-同舟云学术

The case of a μ₂-P aromatic phosphinine as a 4-electron donor forming σ- and π-three–center-two-electron bonds

Published:2024 Issue:12 Volume:53 Page:5608-5615
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Jie¹,Hou Yuanfeng¹,Liu Shihua¹,Lin Jieli¹,Li Zhongshu¹^ORCID

Affiliation:

1. LIFM, IGCME, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China

Abstract

The aromatic μ2-P phosphinine donates four electrons via a σ-lone pair and a high lying π-type electron pair instead of previously reported two σ-lone pairs.

Funder

National Natural Science Foundation of China

Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program

Science and Technology Planning Project of Guangdong Province

Basic and Applied Basic Research Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00228H

Reference58 articles.

1. Phosphinine-based ligands: Recent developments in coordination chemistry and applications

2. Phosphaalkene, phospholyl and phosphinine ligands: New tools in coordination chemistry and catalysis

3. Transition metals in phosphinine chemistry

4. Synthesis and Photoluminescence Properties of an Unprecedented Phosphinine–Cu4Br4 Cluster

5. Gold(i) complexes with a phosphinine ligand: synthesis and structural characterization

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