Deformation-induced phosphorescence shift in a 2D elastically flexible organic single crystal: role of chalcogen-centered weak interactions-Reference-Cited by-同舟云学术

Deformation-induced phosphorescence shift in a 2D elastically flexible organic single crystal: role of chalcogen-centered weak interactions

Published:2022 Issue:35 Volume:13 Page:10308-10314
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bhandary Subhrajyoti¹^ORCID,Van Deun Rik²^ORCID,Kaczmarek Anna M.³^ORCID,Van Hecke Kristof¹^ORCID

Affiliation:

1. XStruct, Department of Chemistry, Ghent University, Krijgslaan 281-S3, 9000 Ghent, Belgium

2. L3 – Luminescent Lanthanide Lab, Department of Chemistry, Ghent University, Krijgslaan 281-S3, 9000 Ghent, Belgium

3. NanoSensing Group, Department of Chemistry, Ghent University, Krijgslaan 281-S3, 9000 Ghent, Belgium

Abstract

In response to macroscopic elastical bending, single crystals of dual emissive dibenzothiophene depict a significant blue shift (∼20 nm) of RTP emission when compared to their pristine crystals (straight and naturally bent).

Funder

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03729G

Reference50 articles.

1. Crystal Adaptronics: Mechanically Reconfigurable Elastic and Superelastic Molecular Crystals

2. The Rise of the Dynamic Crystals

3. From Molecules to Interactions to Crystal Engineering: Mechanical Properties of Organic Solids

4. Elastically flexible molecular crystals

5. Potential and challenges of engineering mechanically flexible molecular crystals

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