Flexible polyfluorinated bis-diazirines as molecular adhesives

Author:

Simhadri Chakravarthi1234,Bi Liting1234ORCID,Lepage Mathieu L.1234ORCID,Takaffoli Mahdi5674ORCID,Pei Zhipeng1674,Musolino Stefania F.1234ORCID,Milani Abbas S.5674,DiLabio Gino A.1674ORCID,Wulff Jeremy E.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Victoria

3. Victoria

4. Canada

5. Materials and Manufacturing Research Institute

6. University of British Columbia

7. Kelowna

Abstract

Flexible, highly fluorinated covalent adhesives are synthesized, and are shown to afford comparable C–H insertion efficiency and adhesion strength relative to a rigid analogue, while providing improved mechanical compliance in the adhesion layer.

Funder

Mitacs

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference43 articles.

1. L. F. M. da Silva , A.Öchsner and R. D.Adams , Handbook of Adhesion Technology , Springer , Berlin , 2011 , vol. 2

2. J. Comyn , in Handbook of Adhesives and Sealants , ed. P. Cognard , Elsevier Science Ltd. , 2006 , vol. 2 , pp. 1–50

3. G. L. Jialanella , in Advances in Structural Adhesive Bonding , ed. D.A. Dillard , Woodhead Publishing , 2010 , pp. 237–264

4. Weak Bonds in a Biomimetic Adhesive Enhance Toughness and Performance

5. S. Ebnesajjad , in Handbook of Adhesives and Surface Preparation , ed. S. Ebnesajjad , William Andrew Publishing , 2011 , pp. 137–183

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