Covalent modification of franckeite with maleimides: connecting molecules and van der Waals heterostructures

Author:

Villalva Julia12345ORCID,Moreno-Da Silva Sara12345ORCID,Villa Palmira67895,Ruiz-González Luisa10117129,Navío Cristina12345,Garcia-Orrit Saül12345ORCID,Vega-Mayoral Víctor12345ORCID,Cabanillas-González Juan12345ORCID,Castellanos-Gomez Andrés13141534ORCID,Giovanelli Emerson12345ORCID,Pérez Emilio M.12345ORCID

Affiliation:

1. IMDEA Nanociencia

2. c/Faraday 9

3. Campus de Cantoblanco

4. Madrid 28049

5. Spain

6. Instituto Pluridisciplinar

7. Universidad Complutense de Madrid

8. Paseo de Juan XXIII No 1

9. Madrid 28040

10. Departamento de Química Inorgánica

11. Facultad de Ciencias Químicas

12. Av. Complutense s/n

13. Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC)

14. Sor Juana Inés de la Cruz

15. 3

Abstract

We show that thiol–ene-like “click” chemistry can be used to decorate franckeite, a naturally occurring van der Waals heterostructure with maleimide reagents. In this way, we provide a pathway towards 2D–2D–0D mixed-dimensional heterostructures.

Funder

H2020 European Research Council

Consejería de Educación, Juventud y Deporte, Comunidad de Madrid

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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