Explosive Werner-type cobalt(iii) complexes
Author:
Affiliation:
1. Chemisches Institut der Otto-von-Guericke-Universität Magdeburg
2. 39106 Magdeburg, Germany
3. Institut für Anorganische und Analytische Chemie der TU Braunschweig
4. 38106 Braunschweig, Germany
5. Nammo Germany GmbH
6. 39218 Schönebeck, Germany
Abstract
A series of potentially explosive Werner-type cobalt(iii) complexes comprising the anions azotetrazolate, nitrotetrazolate, picrate and dipicrylamide have been prepared via simple metathetical routes. Representative studies of the energetic properties (impact and friction sensitivity, combustion) revealed that some of the new compounds are primary explosives.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/QI/C4QI00094C
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