Amphiphilic electrolyte additive as an ion-flow stabilizer enables superb zinc metal batteries

Author:

Yang Zimin12,Sun Yilun1,Deng Siting13,Tong Hao12,Wu Mingqiang13,Nie Xinbin4,Su Yifan4,He Guanjie5ORCID,Zhang Yinghe6,Li Jianwei4,Chai Guoliang17ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002 Fujian, P. R. China

2. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, Fujian, P. R. China

3. College of Chemistry, Fuzhou University, Fuzhou 350108, China

4. Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Province Key Laboratory of Resources and Chemistry of Salt Lakes, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining, Qinghai 810008, P. R. China

5. Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, Torrington Place, London, WC1E 7JE, UK

6. Shenzhen Key Laboratory of Advanced Functional Carbon Materials Research and Comprehensive Application, School of Science, Harbin Institute of Technology, Shenzhen 518055, China

7. School of Chemical Science, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

3-(Hydroxy(phenyl)phosphoryl)propanoic acid (HPA) has a strong coordination ability for Zn2+/metal anodes which not only form sphere micelles that promote the uniform transmission of Zn2+ but also enhance the preferential adsorption on anodes.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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