Probing the factors that influence the conformation of a guanidinato ligand in [(η5-C5Me5)M(NN)X] (NN = chelating N,N′,N′′-tri(o-substituted aryl)guanidinate(1−); X = chloro, azido and triazolato)-Reference-Cited by-同舟云学术

Probing the factors that influence the conformation of a guanidinato ligand in [(η5-C5Me5)M(NN)X] (NN = chelating N,N′,N′′-tri(o-substituted aryl)guanidinate(1−); X = chloro, azido and triazolato)

Published:2018 Issue:3 Volume:42 Page:1853-1866
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kumar Robin¹²³⁴^ORCID,Kishan Ram¹²³⁴,Thomas Jisha Mary⁵¹⁶⁷⁴,Chinnappan Sivasankar⁵¹⁶⁷⁴,Thirupathi Natesan¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Delhi

3. Delhi 110 007

4. India

5. Catalysis and Energy Laboratory

6. Pondicherry University (A Central University)

7. Puducherry 605014

Abstract

The conformational difference illustrated is ascribed to a subtle repulsive interaction between the o-Cl substituent of two proximal aryl rings in the guanidinate ligand.

Funder

Science and Engineering Research Board

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C7NJ03766J

Reference45 articles.

1. Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 21. Neutral and cationic β-diketonato-, η3-allylic, and NN″-triazenido-complexes: the X-ray crystal structure of the binuclear complex [Rh2(C5Me5)2(acac)2][BF4]2

2. Iridium (III) 1,3-bis(aryl)triazenide complexes: Synthesis, characterization and structure