Reactivity of azido terpyridine Pd(<scp>ii</scp>) and Pt(<scp>ii</scp>) complexes towards 4,4,4-trifluoro-2-butynoic acid: structural insight into the triazolato coordination mode-Reference-Cited by-同舟云学术

Reactivity of azido terpyridine Pd(ii) and Pt(ii) complexes towards 4,4,4-trifluoro-2-butynoic acid: structural insight into the triazolato coordination mode

Published:2023 Issue:49 Volume:13 Page:34826-34835
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Mansour Ahmed M.¹^ORCID,Radacki Krzysztof²^ORCID,Mostafa Gamal A. E.³,Ali Essam A.³,Shehab Ola R.⁴^ORCID

Affiliation:

1. Department of Chemistry, United Arab Emirates University, Al-Ain, United Arab Emirates

2. Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

3. Department of Pharmaceutical Chemistry, College of Pharmacy, King Saud University, Riyadh 11451, Saudi Arabia

4. Department of Chemistry, Faculty of Science, Cairo University, Gamma Street, Giza, 12613, Egypt

Abstract

The binuclear azido terpyridine Pd(ii) complex underwent the catalyst-free cycloaddition coupling with alkyne affording triazolate analogues. The coordination mode of the triazolate ring was assigned with the aid of quantum chemical calculations.

Funder

King Saud University

United Arab Emirates University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RA/D3RA06656H

Reference38 articles.

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4. Zur Reaktoin von Azido‐Metallverbindungen: Tetrazolato‐Metallkomplexe

5. Sulfur-nitrogen-bonded metal chelates. 18. 1,3-Dipolar cycloadditions to coordinated azide in nickel(II) complexes of the types [Ni(S-N-N)(N3)] and [S-N-N)Ni(N3)Ni(N-N-S)](ClO4)

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