Metal ion promoted tautomerization and C–N bond cleavage: conversion of catechol to a p-benzoquinone derivative

Author:

Saha Pinaki123,Saha Roy Amit123,Weyhermüller Thomas45,Ghosh Prasanta123

Affiliation:

1. Department of Chemistry

2. R. K. Mission Residential College

3. Kolkata-103, India

4. Max-Planck-Institut für Chemische Energiekonversion

5. , Germany

Abstract

Metal ion promoted conversion of catechol to a p-quinone derivative is reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference25 articles.

1. Non-innocent ligands in bioinorganic chemistry—An overview

2. Studies on charge distribution and valence tautomerism in transition metal complexes of catecholate and semiquinonate ligands

3. J. Q. Chambers , in The Chemistry of Quinonoid Compounds , ed. S. Patai and Z. Rappaport , Wiley , New York , 1988 , vol. II, p. 719

4. Transition metal complexes of o-benzoquinone, o-semiquinone, and catecholate ligands

5. Electron Transfer in Inorganic, Organic and Biological Systems , ed. J. R. Bolton , N. Mataga and G. McLendon , American Chemical Society , Washington, DC , 1991 , vol. 228

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