A rhodium(<scp>ii</scp>)/rhodium(<scp>iii</scp>) redox couple for C–H bond amination with alkylazides: a rhodium(<scp>iii</scp>)–nitrenoid intermediate with a tetradentate [14]-macrocyclic ligand-Reference-Cited by-同舟云学术

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A rhodium(ii)/rhodium(iii) redox couple for C–H bond amination with alkylazides: a rhodium(iii)–nitrenoid intermediate with a tetradentate [14]-macrocyclic ligand

Published:2024 Issue:4 Volume:53 Page:1607-1615
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sugimoto Hideki¹^ORCID,Sakaida Megumu¹,Shiota Yoshihito²^ORCID,Miyanishi Mayuko²,Morimoto Yuma¹^ORCID,Yoshizawa Kazunari²^ORCID,Itoh Shinobu¹^ORCID

Affiliation:

1. Department of Molecular Chemistry, Division of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka, Suita, Osaka 565-0871, Japan

2. Institute for Materials Chemistry and Engineering and International Research Center for Molecular System, Kyushu University, Motooka, Nishi-ku, Fukuoka, 819-0395, Japan

Abstract

The catalytic activity of a rhodium(ii) dimer complex, [RhII(TMAA)]2 (TMAA = tetramethyltetraaza[14]annulene), in C–H amination reactions with organic azides is explored.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03429A

Reference48 articles.

1. Rhodium-Catalyzed C–H Amination. An Enabling Method for Chemical Synthesis

2. Catalytic C–H amination: the stereoselectivity issue

3. Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

4. Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups

5. Intramolecular C(sp3)–H amination

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