Defluorinative alkylation of 1-trifluoromethyl alkenes with alkyl radicals derived from visible light-induced deoxygenation of xanthate salts: synthesis of <i>gem</i>-difluoroalkenes-Reference-Cited by-同舟云学术

Defluorinative alkylation of 1-trifluoromethyl alkenes with alkyl radicals derived from visible light-induced deoxygenation of xanthate salts: synthesis of gem-difluoroalkenes

Published:2023 Issue:16 Volume:21 Page:3330-3334
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Li Xin¹,Jiao Yan¹,Han Lifei²,Sun Jinwei¹,Zhang Xuan¹^ORCID

Affiliation:

1. School of Chemistry and Materials Science, Institute of Advanced Materials and Flexible Electronics (IAMFE), Nanjing University of Information Science and Technology, 219 Ningliu Road, Nanjing 210044, China

2. Breast Disease Center, Zhongda Hospital, School of Medicine, Southeast University, Nanjing 210009, China

Abstract

A visible light-induced deoxygenative difluoroallylation of alcohols via xanthate salts with trifluoromethyl alkenes under catalyst- and metal-free conditions is presented.

Funder

Nanjing University of Information Science and Technology

Jiangsu Provincial Department of Education

Recruitment Program of Global Experts

National Natural Science Foundation of China

Shuangchuang Program of Jiangsu Province

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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