Synthesis of well-defined yttrium-based Lewis acids by capturing a reaction intermediate and catalytic application for cycloaddition of CO2 to epoxides under atmospheric pressure-Reference-Cited by-同舟云学术

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Synthesis of well-defined yttrium-based Lewis acids by capturing a reaction intermediate and catalytic application for cycloaddition of CO2 to epoxides under atmospheric pressure

Published:2019 Issue:21 Volume:9 Page:6152-6165
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Sodpiban Ounjit¹²³⁴⁵,Del Gobbo Silvano¹²³⁴⁵^ORCID,Barman Samir⁶⁷⁸⁹,Aomchad Vatcharaporn¹²³⁴⁵,Kidkhunthod Pinit¹⁰¹¹⁵,Ould-Chikh Samy⁶⁷⁸⁹^ORCID,Poater Albert¹²¹³¹⁴¹⁵^ORCID,D'Elia Valerio¹²³⁴⁵^ORCID,Basset Jean-Marie⁶⁷⁸⁹^ORCID

Affiliation:

1. Department of Material Science and Engineering

2. School of Molecular Science and Engineering

3. Vidyasirimedhi Institute of Science and Technology (VISTEC)

4. Rayong

5. Thailand

6. KAUST Catalysis Center (KCC)

7. King Abdullah University of Science & Technology

8. 23955-6900 Thuwal

9. Saudi Arabia

10. Synchrotron Light Research Institute (Public Organization)

11. Nakhon Ratchasima 30000

12. Institut de Química Computacional i Catàlisi and Departament de Química

13. Universitat de Girona

14. 17003 Girona

15. Spain

Abstract

Single-site yttrium complexes were prepared by immobilization of an intermediate of cycloaddition of CO₂ to epoxides and applied in catalysis.

Funder

Thailand Research Fund

Ministerio de Economía y Competitividad

Vidyasirimedhi Institute of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CY/C9CY01642B

Reference125 articles.

1. Isoprene Regioblock Copolymerization: Switching the Regioselectivity by the in Situ Ancillary Ligand Transmetalation of Active Yttrium Species

2. Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes

3. Yttrium-Catalyzed Regioselective α-C–H Silylation of Methyl Sulfides with Hydrosilanes

4. Intramolecular alkene hydroamination and degradation of amidines: divergent behavior of rare earth metal amidinate intermediates

5. Enantioselective Desymmetrization ofmeso-Aziridines with TMSN3or TMSCN Catalyzed by Discrete Yttrium Complexes

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