Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes-Reference-Cited by-同舟云学术

Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes

Published:2018 Issue:58 Volume:54 Page:8024-8031
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ligny Romain¹²³⁴⁵,Hänninen Mikko M.⁶⁷⁸⁹^ORCID,Guillaume Sophie M.¹²³⁴⁵^ORCID,Carpentier Jean-François¹²³⁴⁵^ORCID

Affiliation:

1. Univ. Rennes

2. CNRS

3. Institut des Sciences Chimiques de Rennes

4. UMR 6226

5. F-35042 Rennes

6. University of Jyväskylä

7. Department of Chemistry

8. FI-40014

9. Finland

Abstract

Electronic vs. steric effects of ligand ortho-substituents in (bis)phenolate yttrium-based complexes for preparation of a large scope of stereoregular poly(3-hydroxyalkanoate)s.

Funder

Academy of Finland

Université de Rennes 1

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC03842B

Reference58 articles.

1. Polymerization of lactide and related cyclic esters by discrete metal complexes

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5. Single site catalysts for stereoselective ring-opening polymerization of lactides

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