Application of multifunctional silylenes and siliranes as universal crosslinkers for metal-free curing of silicones

Author:

Herz Fabian A. D.12341,Nobis Matthias12341,Wendel Daniel12341,Pahl Philipp1234,Altmann Philipp J.1534,Tillmann Jan6784,Weidner Richard6784,Inoue Shigeyoshi1934ORCID,Rieger Bernhard12341ORCID

Affiliation:

1. Technical University of Munich

2. WACKER-Chair of Macromolecular Chemistry

3. 85748 Garching bei München

4. Germany

5. Catalysis Research Center

6. WACKER Chemie AG

7. Consortium für elektrochemische Industrie

8. 81379 München

9. WACKER-Institute of Silicon Chemistry

Abstract

Multifunctional silacyclopropanes act as universal crosslinkers for PDMS-elastomers, which can react via ring-opening or silylene insertion.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference31 articles.

1. M. A. Brook , Silicon in Organic, Organometallic, and Polymer Chemistry , Wiley & Sons Ltd , New York , 1999

2. N. R. Council , The Role of the Chemical Sciences in Finding Alternatives to Critical Resources: A Workshop Summary , The National Academies Press , Washington, DC , 2012

3. Selective and Efficient Platinum(0)-Carbene Complexes As Hydrosilylation Catalysts

4. Decamethylsilicocene-Synthesis and Structure

5. N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis

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