Selective and Efficient Platinum(0)-Carbene Complexes As Hydrosilylation Catalysts-Reference-Cited by-同舟云学术

Selective and Efficient Platinum(0)-Carbene Complexes As Hydrosilylation Catalysts

Published:2002-10-04 Issue:5591 Volume:298 Page:204-206
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Markó István E.¹,Stérin Sébastien²,Buisine Olivier²,Mignani Gérard²,Branlard Paul²,Tinant Bernard³,Declercq Jean-Paul³

Affiliation:

1. Unité de Chimie Organique et Médicinale and

2. Rhodia Silicones, Avenue des Frères Perret 55, F69192 Saint-Fons Cedex, France.

3. Unité d'Analyse Structurale, Département de Chimie, Université Catholique de Louvain, Place Louis Pasteur 1, 1348 Louvain-la-Neuve, Belgium.

Abstract

The hydrosilylation reaction enables the production of silicon polymers. Platinum-carbene complexes are reported that catalyze the hydrosilylation reaction of alkenes with remarkable efficiency and exquisite selectivity and avoid the formation of platinum colloids. By-products, typically encountered with previous catalytic systems, are suppressed with these platinum derivatives.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference32 articles.

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3. I. Ojima in The Chemistry of Organic Silicon Compounds S. Patai Z. Rappoport Eds. (Wiley-Interscience New York 1989) vol. 2 chap. 25 pp. 1479–1526.

4. L. N. Lewis J. Stein Y. Gao R. E. Colborn G. Hutchins Platinum Met. Rev. 41 66 (1997 ).

5. D. A. Armitage in Comprehensive Organometallic Chemistry G. Wilkinson F. G. A. Stone E. W. Abel Eds. (Pergamon Oxford 1982) vol. 2 p. 117.

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