Signatures of technetium oxidation states: a new approach

Author:

Bauters Stephen12345ORCID,Scheinost Andreas C.12345ORCID,Schmeide Katja5678ORCID,Weiss Stephan5678ORCID,Dardenne Kathy910118ORCID,Rothe Jörg910118,Mayordomo Natalia5678ORCID,Steudtner Robin5678ORCID,Stumpf Thorsten5678,Abram Ulrich1213148ORCID,Butorin Sergei M.1516171819ORCID,Kvashnina Kristina O.12345ORCID

Affiliation:

1. The Rossendorf Beamline at ESRF – The European Synchrotron

2. CS40220

3. 38043 Grenoble Cedex 9

4. France

5. Helmholtz-Zentrum Dresden-Rossendorf (HZDR)

6. Institute of Resource Ecology

7. 01328 Dresden

8. Germany

9. Karlsruhe Institute of Technology (KIT)

10. Institute for Nuclear Waste Disposal (INE)

11. D-76021 Karlsruhe

12. Freie Universität Berlin

13. Institute of Chemistry and Biochemistry

14. D-14195 Berlin

15. Molecular and Condensed Matter Physics

16. Department of Physics and Astronomy

17. Uppsala University

18. Uppsala

19. Sweden

Abstract

A general strategy for the determination of Tc oxidation state by a new approach involving X-ray absorption near edge spectroscopy (XANES) at the Tc L3 edge is shown.

Funder

H2020 European Research Council

Vetenskapsrådet

Bundesministerium für Wirtschaft und Energie

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference32 articles.

1. Some Chemical Properties of Element 43

2. R. Alberto , in Comprehensive Coordination Chemistry II, From Biology to Nanotechnology , ed. J. A. McCleverty and T. J. Meyer , Elsevier , 2005 , pp. 127–270

3. A. P. Sattelberger , B. L.Scott and F.Poineau , in Comprehensive Organometallic Chemistry III, From Fundamentals to Applications , ed. D. M. P. Mingos and R. H. Crabtree , Elsevier , 2007 , pp. 833–853

4. Technetium and rhenium: coordination chemistry and nuclear medical applications

5. Technetium and Gallium Derived Radiopharmaceuticals: Comparing and Contrasting the Chemistry of Two Important Radiometals for the Molecular Imaging Era

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