K3[MO4][MO3N] (M=Tc, Re) – Nitridotrioxidorhenate and ‐technetate from Highly Alkaline Media-Reference-Cited by-同舟云学术

K₃[MO₄][MO₃N] (M=Tc, Re) – Nitridotrioxidorhenate and ‐technetate from Highly Alkaline Media

Published:2023-07-24 Issue:26 Volume:26 Page:
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur J Inorg Chem

Author:

Badea Désirée¹^ORCID,Olthof Selina¹^ORCID,Neudörfl Jörg M.¹,Glaum Robert²^ORCID,Pöttgen Rainer³,Reimann Maximilian Kai³,Meerholz Klaus¹^ORCID,Reimer Max¹,Logemann Christian¹^ORCID,Strub Erik¹^ORCID,Bruns Jörn¹^ORCID

Affiliation:

1. Department of Chemistry University of Cologne Greinstrasse 4–6 50939 Cologne Germany

2. Institute of Inorganic Chemistry University of Bonn Gerhard-Domagk-Strasse 1 53121 Bonn Germany

3. Institut für Anorganische und Analytische Chemie Universität Münster Corrensstrasse 30 48149 Münster Germany

Abstract

AbstractThe reactions of ammonium perrhenate and pertechnetate in highly alkaline medium led to the isotypic mixed anionic nitridotrioxidorhenate and ‐technetate K3[MO4][MO3N] (M= Tc, Re). Both compounds occur as colorless crystals, which were investigated by single crystal X‐ray diffraction. Furthermore, K3[ReO4][ReO3N] has been studied by means of X‐ray photoelectron spectroscopy to determine the oxidation state of rhenium. The obtained results have been complemented by magnetic measurements. IR and Raman spectroscopy indicated the presence of Re−O as well as Re−N bonds.

Publisher

Wiley

Subject

Inorganic Chemistry

Reference85 articles.

2. Hydroflux Crystal Growth of Platinum Group Metal Hydroxides: Sr6NaPd2(OH)17, Li2Pt(OH)6, Na2Pt(OH)6, Sr2Pt(OH)8, and Ba2Pt(OH)8

3. Crystal Growth of New Hexahydroxometallates Using a Hydroflux

4. Alkaline-Earth Rhodium Hydroxides: Synthesis, Structures, and Thermal Decomposition to Complex Oxides