Aryl iodine-catalysed divergent synthesis of isobenzofuranones and isocoumarins <i>via</i> oxidative 1,2-aryl migration/elimination-Reference-Cited by-同舟云学术

Aryl iodine-catalysed divergent synthesis of isobenzofuranones and isocoumarins via oxidative 1,2-aryl migration/elimination

Published:2022 Issue:65 Volume:58 Page:9096-9099
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

He Jiaxin¹,Zhang Jingran¹,Li Xuemin¹,Shi Haofeng¹,Du Yunfei¹^ORCID

Affiliation:

1. School of Pharmaceutical Science and Technology, Tianjin University, Tianjin 300072, China

Abstract

The divergent synthesis of isobenzofuranones and isocoumarins from 2-alkenyl benzoic acids was realized via an aryl iodine catalysed oxidative 1,2-aryl migration/elimination enabled by a modified Koser reagent generated in situ.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03101A

Reference58 articles.

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2. Organohypervalent Iodine: Development, Applications, and Future Directions

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4. Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp2 and Benzylic sp3 C–H Bond Imidation

5. Oxidative rearrangements of arylalkenes with [hydroxy(tosyloxy)iodo]benzene in 95% methanol: a general, regiospecific synthesis of α-aryl ketones

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