Understanding and tuning the electronic structure of pentalenides-Reference-Cited by-同舟云学术

Understanding and tuning the electronic structure of pentalenides

Published:2024 Issue:32 Volume:15 Page:12765-12779
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jenek Niko A.¹^ORCID,Helbig Andreas²,Boyt Stuart M.¹^ORCID,Kaur Mandeep¹^ORCID,Sanderson Hugh J.¹^ORCID,Reeksting Shaun B.³^ORCID,Kociok-Köhn Gabriele³^ORCID,Helten Holger²^ORCID,Hintermair Ulrich¹^ORCID

Affiliation:

1. Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK

2. Institute of Inorganic Chemistry, Institute for Sustainable Chemistry & Catalysis with Boron (ICB), Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

3. Chemical Characterisation Facility, University of Bath, Claverton Down, Bath BA2 7AY, UK

Abstract

We report the first systematic study of substituent effects on the electronic structure of pentalenides, giving insight into charge distribution, aromaticity and polarisation effects.

Funder

Royal Society

University of Bath

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC04622B

Reference43 articles.

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4. Reversible Binding and Reduction of Dinitrogen by a Uranium(III) Pentalene Complex

5. Double CO2 activation by 14-electron η8-permethylpentalene titanium dialkyl complexes

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