Tetraphenylpentalenide organolanthanide complexes-Reference-Cited by-同舟云学术

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Tetraphenylpentalenide organolanthanide complexes

Published:2024 Issue:72 Volume:60 Page:9749-9752
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Katzer Nicholas J.¹²^ORCID,Kaur Mandeep³^ORCID,Sen Asmita⁴^ORCID,Nimaiyar Rupal¹,Autschbach Jochen⁴^ORCID,Arnold Polly L.¹²^ORCID,Hintermair Ulrich³^ORCID

Affiliation:

1. Department of Chemistry, University of California, Berkeley, CA, 94720, USA

2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

3. Department of Chemistry, University of Bath, BA2 7AY, UK

4. Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA

Abstract

Lanthanide sandwiches of the D2h 1,3,4,6-tetraphenylpentalenide are reported. The Ph4Pn dianion shows promise for new electron-rich f-block organometallics using the metal's dz2 orbital, in contrast to the more widely used cyclooctatetraenyl dianion.

Funder

Office of Science

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02570A

Reference44 articles.

1. At Least 60 Years of Ferrocene: The Discovery and Rediscovery of the Sandwich Complexes

2. The Vibrancy and Variety of Modern f-Element Organometallic Chemistry

3. Strategies toward High-Temperature Lanthanide-Based Single-Molecule Magnets

4. Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II)

5. Back to the future of organolanthanide chemistry

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