A Lewis acidity adjustable organic ammonium cation derived robust protecting shield for stable aqueous zinc-ion batteries by inhibiting the tip effect

Author:

Qian Siyi1,Zhou Jinqiu1ORCID,Peng Mingji2,Qian Yijun3,Meng Yuan1,Jiang Yuzhuo1,Zeng Xu1,Liu Jie1,Qian Tao14ORCID,Yan Chenglin24ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China

2. Soochow Institute for Energy and Materials Innovations, College of Energy, Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, China

3. Institute for Frontier Materials, Deakin University, Geelong, Victoria 3220, Australia

4. Light Industry Institute of Electrochemical Power Sources, Suzhou 215006, China

Abstract

We explore the effect of organic ammonium cations with different Lewis acidity on the tip effect. Tetraethylammonium cations with medium Lewis acidity can form the most robust protecting shield, thus inhibiting the growth of dendrites.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Nantong University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

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