Can the Ti(OiPr)4/nBuLi combination of reagents function as a catalyst for [2+2+2] alkyne cyclotrimerisation reactions?-Reference-Cited by-同舟云学术

Can the Ti(OiPr)4/nBuLi combination of reagents function as a catalyst for [2+2+2] alkyne cyclotrimerisation reactions?

Published:2018 Issue:24 Volume:42 Page:20219-20226
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Siemiaszko Gabriela¹²³⁴⁵,Six Yvan¹²³⁴⁵^ORCID

Affiliation:

1. Laboratoire de Synthèse Organique (LSO)

2. UMR 7652 CNRS/ENSTA/École Polytechnique

3. Université Paris-Saclay

4. 91128 Palaiseau Cedex

5. France

Abstract

Catalysis of the cyclotrimerisation of alkynes with the Ti(OiPr)₄/nBuLi system was studied, leading to the development of a particularly convenient and reliable protocol.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ04931A

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3. Synthetic transformations mediated by the combination of titanium(IV) alkoxides and Grignard reagents: selectivity issues and recent applications. Part 2: Reactions of alkenes, allenes and alkynes

4. J. K. Cha and O. G. Kulinkovich , in Organic Reactions , ed. S. E. Denmark , John Wiley & Sons , 2012 , vol. 77, ch. 1

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