Choosing between Ti(<scp>ii</scp>) and Ti(<scp>iii</scp>): selective reduction of titanocene dichloride by elemental lanthanides-Reference-Cited by-同舟云学术

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Choosing between Ti(ii) and Ti(iii): selective reduction of titanocene dichloride by elemental lanthanides

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bousrez Guillaume¹²^ORCID,Harakat Dominique¹^ORCID,Chevreux Sylviane¹³,Déchamps-Olivier Isabelle¹,Jaroschik Florian¹⁴^ORCID

Affiliation:

1. Université de Reims Champagne Ardenne, CNRS UMR 7312, ICMR, URCATech, 51100 Reims, France

2. Department of Biological and Chemical Engineering, Aarhus University, 8000 Aarhus C, Denmark

3. Institut de Recherche de Chimie Paris, UMR CNRS 8247, Chimie ParisTech, PSL University, 75005 Paris, France

4. ICGM, Univ. Montpellier, CNRS, ENSCM, 34090 Montpellier, France

Abstract

The selective reduction of titanocene dichloride to either trivalent or divalent titanocene species depending on the lanthanide metal is described and corroborated by reactivity, ESI-MS, EPR and SCXRD studies.

Funder

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT02004A

Reference92 articles.

1. Synthesis of Organotitanium Complexes from Alkenes and Alkynes and Their Synthetic Applications

2. Titanium and Zirconium in Organic Synthesis , ed. I. Marek , Wiley-VCH , Weinheim , 2002

3. Group 4 Transition Metal Sandwich Complexes: Still Fresh after Almost 60 Years

4. Titanium catalysis for the synthesis of fine chemicals – development and trends

5. Redox chemistry of discrete low-valent titanium complexes and low-valent titanium synthons

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