Access and unprecedented reaction pathways of Li/Cl phosphinidenoid iron(0) complexes-Reference-Cited by-同舟云学术

Access and unprecedented reaction pathways of Li/Cl phosphinidenoid iron(0) complexes

Published:2019 Issue:1 Volume:48 Page:339-345
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schmer Alexander¹²³⁴,Volk Niklas¹²³⁴,Espinosa Ferao Arturo⁵⁶⁷⁸⁹^ORCID,Streubel Rainer¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. University of Bonn

3. D-53121 Bonn

4. Germany

5. Departamento de Química Orgánica

6. Facultad de Química

7. Universidad de Murcia

8. E-30100 Murcia

9. Spain

Abstract

Complexes [Fe(CO)₄(RPCl₂)] (2) (a: R = CPh₃, b: R = ^tBu) were used to generate the first examples of phosphinidenoid iron(0) complexes [Li(12-crown-4)(solv)_n][Fe(CO)₄(RPCl] (3a,b), characterized by NMR spectroscopy.

Funder

Deutsche Forschungsgemeinschaft

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04417A

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